Post Doc

Current PhD Students

Previous PhD Students

Research Interests

Collaborations

Financed Projects

  Academic Projects
            Recent Projects
            Former Projects

  Industrial Contracts
            Recent Projects
            Former Projects


 TECAT - Centre d'Innovació en Catàlisi - Transition Metal catalysts for selective and sustainable processes
 

PREVIOUS PAPERS (1990-1999)

Authors: Solé, J.; Bo, C.; Claver, C.; Ruiz, A.
Title: Influence of different ligands in homogeneous hydrogenation using iridium complexes with thioether ligands
Journal of Molecular Catalysis 1990, 61, 163-171


Authors: Polo, A.; Real, J.; Claver, C.; Castillón Miranda, S.; Bayón, J.C.
Title: Low pressure selective hydroformylation of 2,3 and 2,5 -dihydrofuran with a rhodium catalyst. Unexpected influence of the auxiliary ligand tri (ortho-tert-butylphenyl)phosphite
Journal of the Chemical Society D-Chemical Communications 1990, 600-601
Authors: Claver, C.; Ruiz, A.; Masdeu, A.M.; Ruiz, N.
Title: Modified precursor systems for the hydroformylation of olefines
Inorganica Chimica Acta 1990, 175, 77-81
Authors: Claver, C.; Masdeu, A.M.; Ruiz, N.; Foces-Foces, C.; Cano, F.H.; Apreda, M.C.; Oro, L.A.; García-Alejandre, J.; Torrens, H.
Title: Catalytic activity of some fluorothiolate derivatives of rhodium (I). Crystal structure of [Rh(SC6H4F)(CO)2]2
Journal of Organometallic Chemistry 1990, 398, 177-186
Authors: Abbassioun, M.; Chaloner, P.A.; Claver, C.; Hitchcock, P.; Masdeu, A.M.; Ruiz, A.; Saballs, T.
Title: Rhodium (I) and iridium (I) complexes of bis (diphenylphosphino) methane disulfide
Journal of Organometallic Chemistry 1991, 403, 229-241
Authors: Bayón, J.C.; Real, J.; Esteban, P.; Claver, C.; Polo, A.; Ruiz, A.; Castillón, S.
Title: Catalytic hydroformylation of alkenes with cationic dinuclear rhodium complexes and the effect of the counterions
Journal of Organometallic Chemistry 1991, 403, 393-399
Authors: Chaloner, P.A.; Claver, C.; Hitchcock, P.B.; Masdeu, A.M.; Ruiz, A.
Title: Orthorhombic crystal form of trans-carbonyl-chloro bis(triphenylphosphine)rhodium (I) dichloromethane solvate
Acta Crystallographica 1991, C47, 1307-1308
Authors: Sinou, D.; Safi, M.; Claver, C.; Masdeu, A.M.
Title: Chiral sulphonated phosphines. Part VII. Catalytic transfer-hidrogenation of unsaturated substrates with formates in the presence of water soluble complex of rhodium
Journal of Molecular Catalysis 1991, 68, L9-L12
Authors: Polo, A.; Fernández, E.; Claver, C.; Castillón Miranda, S.
Title: Hydroformylation of glucal derivatives with rhodium catysts. Crucial influence of the auxiliary ligand tris (ortho-tert-butylphenyl) phosphite
Journal of the Chemical Society D-Chemical Communications 1992, 639-639
Authors: Laghmari, M.; Sinou, D.; Masdeu, A.M.; Claver, C.
Title: Chiral sulfonated phosphines. Part VIII. Hydrogenation of dehydropeptides in a two-phase system
Journal of Organometallic Chemistry 1992, 438, 213-216
Authors: Polo, A.; Claver, C.; Castillón, S.; Ruíz, A.; Bayón, J.C.; Real, J.; Mealli, C.; Masi, D.
Title: Regioselective hydroformylation of cyclic vinyl and allyl ethers with rhodium catalysts. Crucial influence of the size of the phosphorous cocatalyst
Organometallics 1992, 11, 3525-3533
Authors: Masdeu, A.M.; Ruiz, A.; Castillón, S.; Claver, C.; Hitchcock, P.B.; Chaloner, P.A.; Bo Jane, C.; Poblet, J.M.; Sarasa, P.
Title: New dithiolate bridged rhodium complexes
Journal of the Chemical Society-Dalton Transactions 1993, 2689-2696
Authors: Adedapo, A.; Benyunes, S.A.; Chaloner, P.A.; Claver, C.; Hitchcock, P.B.; Ruiz, A.; Ruiz, N.
Title: Rhodium (I) complexes of 4-t-butylcyclohexyldiaziridine and adamatyldiaziridine: synthesis, structure and catalytic activity
Journal of Organometallic Chemistry 1993, 443, 241-247
Authors: Claver, C.; Castillón, S.; Ruiz, N.; Delogu, G.; Fabbri, D.; Gladiali, S.
Title: Asymmetric hydroformylation of styrene by rhodium (I) catalysts with chiral ligands containing sulphur donors
Journal of the Chemical Society D-Chemical Communications 1993, 24, 1833-1834
Authors: Masdeu, A.M.; Orejón, A.; Ruiz, A.; Castillón, S.; Claver, C.
Title: New hydroformylation rhodium catalyst with dithiolate chiral ligands
Journal of Molecular Catalysis 1994, 94, 149-156
Authors: Aaliti, A.; Masdeu, A.M.; Ruiz, A.; Claver, C.
Title: Preparation of carbonyl phosphine rhodium complexes with dithiolate bidges. Application as catalyst precursors in the hydroformylation of 1-hexene
Journal of Organometallic Chemistry 1995, 489, 101-106
Authors: Claver, C.; Ruiz, N.; Lahuerta, P.; Peris, E.
Title: Dinuclear Rh (II) complexes in styrene hydroformylation. Enhancement of catalytic activity through orthometalation
Inorganica Chimica Acta 1995, 233, 161-164
Authors: Fernández, E.; Ruíz, A.; Castillón, S.; Claver, C.; Piniella, A.; Álvarez-Larena, A.; Germain, G.
Title: Preparation, Structure and Reactivity of Dinuclear Aminothiolate-bridge Iridium Complexes
Journal of the Chemical Society-Dalton Transactions 1995, 2137-2142
Authors: Gladiali, S.; Bayón, J.C.; Claver, C.
Title: Recent Advances in Enantioselective hydroformylation
Tetrahedron-Asymmetry 1995, 6, 1453-1474
Authors: Masdeu Bultó, A.M.; Orejón, A.; Castillón Miranda, S.; Claver, C.
Title: Asymmetric hydroformylation of styrene using dithiolato bridged dirhodium catalyst with BDPP as chiral ligand
Tetrahedron-Asymmetry 1995, 6, 1885-1888
Authors: Ruiz, N.; Castillón, S.; Ruiz, A.; Claver, C.; Aaliti, A.; Alvarez-Larena, A.; Piniella, J.F.; Germain, G.
Title: Synthesis and characterization of rhodium complexes containing atropisometric sulphur ligands. X-Ray structure of [{Rh2(mL) (CO)3 (P-(OC6H4But-O)3]} 2] (H2L=1,1'-binaphtholene 2,2-dithiol)
Journal of the Chemical Society-Dalton Transactions 1996, 969-973
Authors: Masdeu Bultó, A.M.; Orejón, A.; Castellanos, A.; Castillón Miranda, S.; Claver, C.
Title: Asymmetric hydroformylation of styrene using a rhodium catalyst with BDPP as the chiral ligand
Tetrahedron-Asymmetry 1996, 7, 1829-1834
Authors: Bedford, R.B.; Castillón Miranda, S.; Chaloner, P.A.; Claver, C.; Fernández, E.; Hitchcock, P.B.; Ruiz, A.
Title: Iridium complexes of orthometalated triaryl phosphites: synthesis, structure, reactivity and their use as imine hydrogenation catalysts
Organometallics 1996, 15, 3990-3997
Authors: Montenegro, E.; Echarri, R.; Claver, C.; Castillón Miranda, S.; Moyano, M.A.; Pericàs, A.; Riera, A.
Title: New Camphor-derived sulfur chiral controllers: Synthesis of (2R-exo)-10- methylthio-2-bornanethiol and (2R-exo)-2,10-bis(methylthio)bornane
Tetrahedron-Asymmetry 1996, 7, 3553-3558
Authors: Castellanos-Páez, A.; Castillón Miranda, S.; Claver, C.
Title: Synthesis of rhodium (I) complexes with the new dithiol chiral ligand (+)-trans-2,3 bis (mercaptomethyl)-bicyclo [2.2.2.]octane (H2BCO). Their application as catalyst precursors in styrene hydroformylation
Journal of Organometallic Chemistry 1997, 539, 1-7
Authors: Andrade, J.; García, J.J.; Torrens, H.; del Rio, F.; Claver, C.; Ruiz, N.
Title: Iridium and Rhodium perfluorobenzenethiolato complexes. Syntheses and catalytic behavior
Inorganica Chimica Acta 1997, 255, 389-393
Authors: Echarri, R.; Matheu, M.I.; Claver, C.; Castillón, S.; Álvarez-Larena, A.; Piniella, J.F.
Title: A New Reaction of Tetrabutylammonium Camphorsulphonate with P4S10. Synthesis and Crystal Structure of the First Chiral Tetrathiophosphate Derivative
Tetrahedron Letters 1997, 38, 6457-6460
Authors: Diéguez, M.; Orejón, A.; Masdeu-Bultó, A.; Echarri, R.; Castillón Miranda, S.; Claver, C.; Ruiz, A.
Title: Synthesis and reactivity of cationic iridium(I) complexes of cycloocta-1,5-diene and chiral dithioether ligands. Application as catalyst precursors in asymmetric hydrogenation
Journal of the Chemical Society-Dalton Transactions 1997, 4611-4618
Authors: Ruiz, N.; Aaliti, A.; Forniés Cámer, J.; Ruiz, A.; Claver, C.; Cardin, C.J.; Fabbri, D.; Gladiali, S.
Title: Metal complexes with atropisomeric sulfur ligands in asymmetric hydroformylation. X-ray structure of [Rh2(m-biphes)(COD)2)](H2biphes=4,4'-biphenanthrene-3,3'-dithiol)
Journal of Organometallic Chemistry 1997, 545-546, 79-87
Authors: Forniés-Cámer, J.; Aaliti, A.; Ruiz, N.; Masdeu-Bultó, A.M.; Claver, C.; Cardin, C.J.
Title: Mononuclear Pt(II) and Pd(II) 1,4-dithiolato complexes. Crystal structures of [Pt((-)-DIOS) (PPh3)2] and [Pd(S(CH2)4S)(Ph2P(CH2)3PPh2]. Application in Styrene Hydroformylation
Journal of Organometallic Chemistry 1997, 530, 199-209
Authors: Fernández, E.; Ruiz, A.; Claver, C.; Castillón S.; Polo, A.; Piniella, J.F.; Alvarez-Larena, A.
Title: Regio and stereoselective hydroformylation of Glucal Derivatives with Rhodium Catalysts
Organometallics 1998, 17, 2857-2864
Authors: Castellanos-Paez, A.; Castillón Miranda, S.; Claver, C.; Van Leeuwen, P.W.N.M.; de Lange, W.G.J.
Title: Diphosphine and dithiolate rhodium complexes: characterization of the species under hydroformylation conditions
Organometallics 1998, 17, 2543-2552
Authors: Forniés-Cámer, J.; Masdeu-Bulto, A.M.; Claver, C.; Cardin, C.J.
Title: Mononuclear Pt(II) and Pd(II) dithiolate complexes as chelate metalloligands for Preparation of heterobimetallic d8-d8 complexes
Inorganic Chemistry 1998, 37, 2626-2632
Authors: Castellanos-Paez, A.; Thayaparan, J.; Castillón Miranda, S.; Claver, C.
Title: Reactivity of tetracarbonyl dihiolate bridged rhodium (I) complexes with diphosphines
Journal of Organometallic Chemistry 1998, 551, 375
Authors: Gladiali, S.; Fabbri, D.; Kollàr, L.; Claver, C.; Ruiz, N.; Álvarez-Larena,A.; Piniella, J.F.
Title: Synthesis, structure and dinamic behaviour of transition metal chelate complexes with atropisomeric dithioether ligands
European Journal of Inorganic Chemistry 1998, 1, 113-118
Authors: Orejón, A.; Masdeu-Bultó, A.M.; Echarri, R.; Diéguez, M.; Forniés-Cámer, J.; Claver, C.; Cardin, C.J.
Title: Rhodium cationic complexes using dithioethers as chiral ligands. Application in styrene hydroformylation
Journal of Organometallic Chemistry 1998, 559, 23-29
Authors: Fernández, E.; Polo, A.; Ruiz, A.; Claver, C.; Castillón, S.
Title: Consecutive catalytic hydroformylation-acetalization of glucal derivatives with rhodium-phosphite and pyridiniumtoluene-p-sulfonate as catalysts: Theinfluence of protecting groups
Chemical Communications 1998, 1803-1804
Authors: Kruis, D.; Ruiz, N.; Janssen, M.D.; Boersma, J.; Claver, C.; Van Koten, G.
Title: Highly selective hydrocarboxylation of styrene with oxalic acid or water using palladium ortho-amino arenethiolates with intramolecular coordinating nitrogen Lewis bases
Inorganic Chemistry Communications 1998, 1, 295-298
Authors: Diéguez, M.; Ruiz, A.; Claver, C.; Pereira, M.M.; Rocha Gonsalves, A.M.A.
Title: Iridium complexes with new 1,2-dithioether chiral ligands containing a rigid cyclic bachbone. Application in homogeneous catalytic asymmetric hidrogenation
Journal of the Chemical Society-Dalton Transactions 1998, 3517-3522
Authors: Orejón, A.; Claver, C.; Oro, L.; Elduque, A.; Pinillos, M.T.
Title: Hydroformylation of styrene using thiolato-pyrazolate bridge rhodium catalyst modified with phosphorus ligand
Journal of Molecular Catalysis A-Chemical 1998, 136, 279-284
Authors: Ruiz, N.; Polo, A.; Castillón, S.; Claver, C.
Title: Hydroformylation of allyl ethers. A study of the regioselectivity using rhodium catalysts
Journal of Molecular Catalysis A-Chemical 1999, 137, 93-100
Authors: Forniés-Cámer, J.; Masdeu-Bultó, A.M.; Claver, C.
Title: Heterobimetallic MIr (M=Pt or Pd) dithiolato bridge complexes
Inorganic Chemistry Communications 1999, 2/3, 89-92
Authors: Fernández, E.; Ruiz, A.; Claver, C.; Castillón, S.; Chaloner, P.A.; Hitchcock, P.B.
Title: The synthesis and single-crystal X-ray structure of the first mononuclear iridium carbonyl hydride with two orthometallated phosphite ligands cis-[IrHCOP(O-o-tBuC6H3) (O-o-tBuC6H4)2}2]
Inorganic Chemistry Communications 1999, 2, 21-24
Authors: Ruiz, N.; Del Rio, I.; Jiménez, J.L.; Claver, C.; Forniés-Camer, J.; Cardin, C.J.; Gladiali, S.
Title: High-branched selectivity in the palladium-catalysed alcoxycarbonylation of styrene in the presence of thiol-thioether atropisomeric ligands
Journal of Molecular Catalysis A-Chemical 1999, 143, 171-180
Authors: Miquel Serrano, M.D.; Masdeu-Bultó, A.M.; Claver, C.; Sinou, D.
Title: Asymmetric hydroformylation of styrene with rhodium complexes of sulphonated diphosphines in aqueous systems
Journal of Molecular Catalysis 1999, 143, 49-55
Authors: Diéguez, M.; Claver, C.; Masdeu-Bultó, A.M.; Ruiz, A.; Van Leeuwen, P.W.N.;Schoemaker, G.C.
Title: High Pressure Infrared Studies of rhodium complexes containing thiolate bridge ligands under hydroformylation conditions
Organometallics 1999, 18, 2107-2115
Authors: Diéguez, M.; Pereira, M.M.; Masdeu-Bultó, A.M.; Claver, C.; Bayón, J.C.
Title: Rhodium-diphosphine catalyst for the hydroformylation of styrene: the influence of the excess of ligands and the chelate ring size on the reaction selectivity
Journal of Molecular Catalysis 1999, 143, 111-122
Authors: Bayón, J.C.; Claver, C.; Masdeu-Bultó, A.M.
Title: Homogeneous catalysis with transition metal complexes containing sulfur ligands
Coordination Chemistry Reviews 1999, 193, 73-145
Authors: Fernández, E.; Ruiz, A.; Claver, C.; Castillón, S.; Chaloner, P.A.; Hitchcok, P.B.
Title: Synthesis and structural determination of the stable dinuclear carbonyl-phosphine rhodium(0) complex (CO)2(P(O-o-tBuPh)3)(CO)
Inorganic Chemistry Communications 1999, 2, 283-287
Authors: Casado, M.A.; Pérez-Torrente, J.; Ciriano, M.A.; Oro, L.A.; Orejón, A.; Claver, C.
Title: Early-late heterotetranuclear complexes (TiR3) with bridging sulfidoligands: ligand replacement reactions and catalytic activity in hydroformulation of olefins
Organometallics 1999, 18, 2107-2125
Authors: Pàmies, O.; Net, G.; Wiidhalm, M.; Ruiz, A.; Claver, C.
Title: Rhodium cationic complexes using macrocyclic diphosphines as chiral ligands. Application in asymmetric hydroformylation
Journal of Organometallic Chemistry 1999, 587, 136-141
Authors: Margalef-Català, R.; Salagre, P.; Fernández, E.; Claver, C.
Title: High efficiency and reusability of iridium complexes adsorbed in montmorillonite clay on catalytic hydrogenation of imines
Catalysis Letters 1999, 60, 121-123
Authors: Pàmies, O.; Net, G.; Ruiz, A.; Bo, C.; Poblet, J.M.; Claver, C.
Title: Synthesis of Rh(I) and Ir (I) metal complexes with the first two chiral dithiolate ligands derived form carbohydrates
Journal of Organometallic Chemistry 1999, 586, 125-137
Authors: Pàmies, O.; Ruiz, A.; Net, G.; Claver, C.
Title: Enantioselective copper-catalyzed 1,4-addition of diethylzinc tp cyclohexenone using chiral diphosphite ligands
Tetrahedron-Asymmetry 1999, 10, 2007-2014
Authors: Pamies, O.; Diéguez, M.; Net, G.; Ruiz, A.; Claver, C.
Title: Iridium complexes containing the first sugar dithioether ligands. Application as catalyst precursors in asymmetric hydrogenation
Journal of the Chemical Society-Dalton Transactions 1999, 3439-3444
Authors: Diéguez, M.; Ruiz, A.; Claver, C.; Pereira, M.M.; Flor, M.T.; Bayón, J.C.; Serra, M.E.S.; d'A. Rocha Gonsalves, A.M.
Title: Synthesis, reactivity and catalytic properties of rhodium complexes of (R,R)-1-benzyl-3,4-dithioetherpyrrolidines
Inorganica Chimica Acta 1999, 295, 64-70
Authors: Miquel-Serrano, M. D.; Agmiz, A.; Diéguez, M.; Masdeu-Bultó, A. M.; Claver, C.; Sinou, D.
Title: Recoverable chiral palladium-sulfonated diphosphine catalysts for the asymmetric hydrocarboxylation of vinyl arenes
Tetrahedron-Asymmetry 1999, 10, 4463-4467

 

Universitat Rovira i Virgili

Departament de Física i Química Inorgànica


 

N4 Building - Universitat Rovira i Virgili. Campus Sescelades. Marcel·lí Domingo s/n. - 43007 - Tarragona Spain

Tel. +34 977 55 80 46 / 55 86 27 | Fax. +34 977 55 95 63 | tecat@urv.cat